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Dry cell : ウィキペディア英語版
Dry cell

A Dry cell is a type of chemical cells, commonly used today, in the form of batteries, for many electrical appliances. It was developed in 1886 by the German scientist Karl Gassner.
A dry cell uses a paste electrolyte, with only enough moisture to allow current to flow. Unlike a wet cell, a dry cell can operate in any orientation without spilling, as it contains no free liquid, making it suitable for portable equipment. By comparison, the first wet cells were typically fragile glass containers with lead rods hanging from the open top and needed careful handling to avoid spillage. Lead-acid battery did not achieve the safety and portability of the dry cell until the development of the gel battery.
A common dry cell is the zinc–carbon battery, sometimes called the dry Leclanché cell, with a nominal voltage of 1.5 volts, the same as the alkaline battery (since both use the same zincmanganese dioxide combination).
A standard dry cell comprises a zinc anode, usually in the form of a cylindrical pot, with a carbon cathode in the form of a central rod. The electrolyte is ammonium chloride in the form of a paste next to the zinc anode. The remaining space between the electrolyte and carbon cathode is taken up by a second paste consisting of ammonium chloride and manganese dioxide, the latter acting as a depolariser. In some designs, the ammonium chloride is replaced by zinc chloride.
==History==

Many experimenters tried to immobilize the electrolyte of an electrochemical cell to make it more convenient to use. The Zamboni pile of 1812 was a high-voltage dry battery but capable of delivering only minute currents. Various experiments were made with cellulose, sawdust, spun glass, asbestos fibers, and gelatine.〔W. E. Ayrton ''Practical Electricity; A Laboratory and Lecture Course for First Year ...'' 1897, reprint Read Books, 2008 ISBN 1-4086-9150-7, page 458〕
In 1886, Carl Gassner obtained a German patent (No. 37,758) on a variant of the Leclanché cell, which came to be known as the dry cell because it did not have a free liquid electrolyte. Instead, the ammonium chloride was mixed with Plaster of Paris to create a paste, with a small amount of zinc chloride added in to extend the shelf life. The manganese dioxide cathode was dipped in this paste, and both were sealed in a zinc shell, which also acted as the anode. In November 1887, he obtained for the same device.〔http://todayinsci.com/G/Gassner_Carl/GassnerPatent373064.htm〕
Unlike previous wet cells, Gassner's dry cell was more solid, did not require maintenance, did not spill, and could be used in any orientation. It provided a potential of 1.5 volts. The first mass-produced model was the Columbia dry cell, first marketed by the National Carbon Company in 1896. The NCC improved Gassner's model by replacing the plaster of Paris with coiled cardboard, an innovation that left more space for the cathode and made the battery easier to assemble. It was the first convenient battery for the masses and made portable electrical devices practical.
The zinc-carbon battery (as it came to be known) is still manufactured today.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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